Dr. Paul Marshall

Vita

EDUCATION:

1985 - Ph.D., Physical Chemistry, University of Cambridge
1982 - B.A., Natural Sciences, University of Cambridge

PROFESSIONAL EXPERIENCE:

2005-         - Regents' Professor, Dept. of Chemistry, University of North Texas, Denton, TX
2000-2005 - Professor, Dept. of Chemistry, University of North Texas, Denton, TX
1994-2000 - Associate Professor, Dept. of Chemistry, University of North Texas, Denton, TX
1988-1994 - Assistant Professor, Dept. of Chemistry, University of North Texas, Denton, TX
1987-1988 - Adjunct Assistant Prof., Dept. of Chemical Engineering, Rensselaer Polytechnic Inst., Troy, NY
1985-1988 - Postdoctoral Research Associate, Dept. of Chemical Engineering, Rensselaer Polytechnic Inst., Troy, NY

PROFESSIONAL ACTIVITIES:

Membership in Professional Organizations:

American Chemical Society
Combustion Institute

Honors:

Sugden Award 2013 (The Combustion Institute, British Section)
Developing Scholar award 1996 (UNT)
Top Prof award (UNT) 1994

Areas of Expertise:

Gas-phase chemical kinetics, with emphasis on the isolation of radical reactions and the measurement of the rate constants over wide ranges of temperature by means of time-resolved spectroscopy and fast-flow techniques. The results are interpreted in the light of dynamical theories and ab initio information about potential energy surfaces, obtained using computational quantum chemistry.

PUBLICATIONS:

177 publications.

For a document with links to the open-access full text of the articles click here

  1. "Temperature Dependence of the Absolute Third-Order Rate Constant for the Reaction between Na + O2 + N2 over the Range 571-1016 K Studied by Time-Resolved Atomic Resonance Absorption Spectroscopy", D. Husain, P. Marshall and J. M. C. Plane, J. Chem. Soc. Faraday Trans. 2, 81, 301 (1985).
  2. "Determination of Absolute Rate Data for the Reaction of Atomic Sodium, Na(32S½), with CF3Cl, CF2Cl2, CFCl3, CF3Br and SF6 as a Function of Temperature by Time-Resolved Resonance Absorption Spectroscopy at λ = 589 nm [Na(32PJ) - Na(32S½)]", D. Husain and P. Marshall, J. Chem. Soc. Faraday Trans. 2, 81, 613 (1985).
  3. "Kinetic Study of the Absolute Rate Constant for the Reaction between Na + N2O in the Temperature Range 349-917 K by Time-Resolved Atomic Resonance Absorption Spectroscopy at λ = 589 nm [Na(32PJ) - Na(32S½)] Following Pulsed Irradiation", D. Husain and P. Marshall, Comb. Flame, 60, 81 (1985).
  4. "Determination of the Absolute Second-Order Rate Constant for the Reaction Na + O3 → NaO + O2", D. Husain, P. Marshall and J. M. C. Plane, J. Chem. Soc., Chem. Commun., 1216 (1985).
  5. "Rate Constant for the Reaction Na + O2 + N2 → NaO2 + N2 under Mesospheric Conditions", D. Husain, P. Marshall and J. M. C. Plane, J. Photochem., 32, 1 (1986).
  6. "Determination of Absolute Rate Data for the Reaction of Atomic Sodium, Na(32S½), with CH3F, CH3Cl, CH3Br, HCl and HBr as a Function of Temperature by Time-Resolved Atomic Resonance Spectroscopy", D. Husain and P. Marshall, Int. J. Chem. Kinet., 18, 83 (1986).
  7. "An HTP Kinetics Study of the Reaction between Ground-State H Atoms and NH3 from 500 to 1140 K", P. Marshall and A. Fontijn, J. Chem. Phys., 85, 2637 (1986).
  8. "A High-Temperature Photochemistry Kinetics Study of the Reaction of O(3P) Atoms with Ethylene from 290 to 1510 K", K. Mahmud, P. Marshall and A. Fontijn, J. Phys. Chem., 91, 1568 (1987).
  9. "High-Temperature Photochemistry and BAC-MP4 Studies of the Reaction between Ground-State H Atoms and N2O", P. Marshall, A. Fontijn and C.F. Melius, J. Chem. Phys., 86, 5540 (1987).
  10. "Temperature Dependence of the Absolute Third-Order Rate Constant for the Reaction between K + O2 + N2 over the Range 680-1010 K Studied by Time-Resolved Atomic Resonance Absorption Spectroscopy", D. Husain, Y. H. Lee and P. Marshall, Comb. Flame, 68, 143 (1987).
  11. "A Method for Analyzing Exponential Decays", P. Marshall, Comput. Chem., 11, 219 (1987).
  12. "A High-Temperature Photochemistry (HTP) Study of the D + ND3 Reaction", P. Marshall and A. Fontijn, J. Phys. Chem., 91, 6297 (1987).
  13. "HTP Kinetics Studies of the Reaction of O(23PJ) Atoms with H2 and D2 over Wide Temperature Ranges", P. Marshall and A. Fontijn, J. Chem. Phys., 87, 6988 (1987).
  14. "The Reaction of O(3P) Atoms with Ethane: an HTP Kinetics Study from 300 to 1270 K", K. Mahmud, P. Marshall and A. Fontijn, J. Chem. Phys., 88, 2393 (1988).
  15. "High-Temperature Fast-Flow Reactor Kinetics Studies: Al + Cl2 → AlCl + Cl, Al + HCl → AlCl + H, and AlCl + Cl2 → AlCl2 + Cl", D. F. Rogowski, P. Marshall and A. Fontijn, J. Phys. Chem., 93, 1118 (1989).
  16. "High-Temperature Photochemistry (HTP) Studies of the Reactions of H(12S) and D(12S) with N2O", P. Marshall, T. Ko and A. Fontijn, J. Phys. Chem., 93, 1922 (1989).
  17. "Rate Coefficients for the H + NH3 Reaction over a Wide Temperature Range", T. Ko, P. Marshall and A. Fontijn, J. Phys. Chem., 94, 1401 (1990).
  18. "Kinetic and Thermochemical Studies of the Recombination Reaction Na + O2 + N2 from 590 to 1515 K by a Modified High-Temperature Photochemistry Technique", P. Marshall, A. S. Narayan and A. Fontijn, J. Phys. Chem., 94, 2998 (1990).
  19. "A Kinetic Study of the Recombination Reaction Na + SO2 + Ar", Y. Shi and P. Marshall, J. Phys. Chem., 95, 1654 (1991).
  20. "An Ab Initio Study of the Reaction of Atomic Hydrogen with Sulfur Dioxide", D. Binns and P. Marshall, J. Chem. Phys., 95, 4940 (1991).
  21. "A Computational Study of Adducts between Atomic Chlorine and Carbon Dioxide, Carbonyl Sulfide and Carbon Disulfide", P. Marshall, J. Mol. Struct. (Theochem), 236, 309 (1991).
  22. "An Ab Initio Study of the Ionization of Sodium Superoxide", P. Marshall, J. Chem. Phys., 95, 7773 (1991).
  23. "Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Silane", L. Ding and P. Marshall, J. Phys. Chem., 96, 2197 (1992).
  24. "An Ab Initio Study of Sulfinic Acid and Related Species", D. Laakso and P. Marshall, J. Phys. Chem., 96, 2471 (1992).
  25. "Does Alkyl Substitution Affect the Si-H Bond Strength in Silane? Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Trimethylsilane and an Ab Initio Investigation", L. Ding and P. Marshall, J. Amer. Chem. Soc., 114, 5754 (1992).
  26. "Reactions of Boron and Aluminum Atoms with Small Molecules", P. Marshall, P. B. O'Connor, W.-T. Chan, P. V. Kristof and J. D. Goddard, in "Gas-Phase Metal Reactions" (A. Fontijn, Editor; North Holland, Amsterdam, 1992) Ch. 8.
  27. "A Theoretical Study of Nitrososilane and Six Isomers of SiH3NO", P. Marshall, Chem. Phys. Lett., 201, 493 (1993).
  28. "Kinetic Studies of the Reactions of Atomic Bromine with Methylsilane and Dimethylsilane and Ab Initio Investigations", L. Ding and P. Marshall, J. Chem. Soc. Faraday Trans., 89, 419 (1993).
  29. "Discharge-Flow/Chemiluminescence and Flash-Photolysis/Resonance Fluorescence Studies of the Reaction O + SiH4 at Room Temperature", C. A. Taylor, L. Ding and P. Marshall, Int. J. Chem. Kinet., 25, 183 (1993).
  30. "An Investigation of the Gas-Phase Reaction of Atomic Bromine with Disilane: Implications for the Si2H5-H Bond Strength", A. Goumri, W.-J. Yuan, L. Ding and P. Marshall, Chem. Phys. Lett., 204, 296 (1993).
  31. "Gas-Phase Reactions between Hydrocarbons and Metal Oxides. The AlO + CH4 Reaction from 590 to 1380 K", D. P. Belyung, A. Fontijn and P. Marshall, J. Phys. Chem., 97, 3456 (1993).
  32. "The Kinetics of the Reaction of Atomic Oxygen with Tetramethylsilane", L. Ding and P. Marshall, J. Phys. Chem., 97, 3758 (1993).
  33. "An Investigation of the Gas-Phase Reaction of Trimethylsilyl Radicals with HBr: Measurement of the (CH3)3Si-H Bond Strength", A. Goumri, W.-J. Yuan and P. Marshall, J. Amer. Chem. Soc., 115, 2539 (1993).
  34. "A Discharge-Flow/Chemiluminescence Study of the Reaction O + Si2H6 at Room Temperature", C. A. Taylor and P. Marshall, Chem. Phys. Lett., 205, 493 (1993).
  35. "Experimental and Theoretical Studies of the Reaction of Atomic Oxygen with Silane", L. Ding and P. Marshall, J. Chem. Phys., 98, 8545 (1993).
  36. "An Investigation of the Gas-Phase Kinetics of the Reaction K + SO2 + Ar", A. Goumri, D. Laakso, J-D. R. Rocha, E. Francis and P. Marshall, J. Phys. Chem., 97, 5295 (1993).
  37. "Experimental and Theoretical Studies of the Reaction of Atomic Hydrogen with Silane", A. Goumri, W.-J. Yuan, L. Ding, Y. Shi and P. Marshall, Chem. Phys., 177, 233 (1993).
  38. "A Computational Investigation of the Molecular Geometry and Rotational Barriers in Ethylmethyl Ether", C. L. Stanton, P. Marshall and M. Schwartz, J. Mol. Struct. (Theochem), 288, 215 (1993).
  39. "Investigations of the Reaction of Trimethylsilane with O(3P) Atoms", A. Misra, L. Ding, P. Marshall, C. Buchta, D.-V. Stucken, J.-T. Vollmer and H. Gg. Wagner, J. Phys. Chem., 98, 4020 (1994).
  40. "An Investigation of Donor-Acceptor Bonding between Amines and Silylenes", R. T. Conlin, D. Laakso and P. Marshall, Organometallics, 13, 838 (1994).
  41. "Kinetics and Thermochemistry of the Reaction Si(CH3)3 + HBr = Si(CH3)3H + Br: Determination of the (CH3)3Si-H Bond Energy", I. J. Kalinovski, D. Gutman, L. N. Krasnoperov, A. Goumri, W.-J. Yuan and P. Marshall, J. Phys. Chem., 98, 9551 (1994).
  42. "Theoretical Studies of the RSOO, ROSO, RSO2 and HOOS (R = H, CH3) Radicals", D. Laakso, C. E. Smith, A. Goumri, J.-D. R. Rocha and P. Marshall, Chem. Phys. Lett., 227, 377 (1994).
  43. "Theoretical Studies of Reactions of Silanes", P. Marshall, J. Mol. Struct. (Theochem), 313, 19 (1994).
  44. "Computational Studies of the Potential Energy Surface for O(1D) + H2S: Characterization of Pathways Involving H2SO, HOSH and H2OS", A. Goumri, J.-D. R. Rocha, D. Laakso, C. E. Smith and P. Marshall, J. Chem. Phys., 101, 9405 (1994).
  45. "Computational Studies of the Potential Energy Surface for O(3P) + H2S: Characterization of Transition States and the Enthalpy of Formation of HSO and HOS", A. Goumri, D. Laakso, J.-D. R. Rocha, C. E. Smith and P. Marshall, J. Chem. Phys., 102, 161 (1995).
  46. "The Kinetics of the Recombination Reaction SH + O2 + Ar: Implications for the Formation and Loss of HSOO and SOO in the Atmosphere", A. Goumri, J.-D. R. Rocha and P. Marshall, J. Phys. Chem., 99, 10834 (1995).
  47. "Collision-Induced Interaction Cross Sections of 1-7 MeV B2 Ions Incident on an N2 Gas Target", Y. D. Kim, J. Y Kim, S. Matteson, D. L. Weathers, J. M. Anthony, P. Marshall and F. D. McDaniel, Nucl. Instrum. Methods Phys. Res., 99, 82 (1995).
  48. "The Positions of λ max for some Trimethylsilyl-Substituted Silylenes", S. G. Bott, P. Marshall, P. E. Wagenseller, Y. Yang and R. T. Conlin, J. Organomet. Chem., 499, 11 (1995).
  49. "Ab Initio Calculations and Kinetics Modeling of Halon and Halon Replacements", H.L. Paige, R. J. Berry, M. Schwartz, P. Marshall, D. R. F. Burgess and M. R. Nyden, Proceedings of the Halon Options Technical Working Conference, 259-270 (1996).
  50. "Laser-Induced Fluorescence and Mass-Spectrometric Studies of the Cu + HCl Reaction over a Wide Temperature Range. Formation of HCuCl", D. P. Belyung, J. Hranisavljevic, O. E. Kashireninov, G. M. Santana, A. Fontijn and P. Marshall, J. Phys. Chem., 100, 17835 (1996).
  51. "Kinetic and Mechanistic Studies of the Reaction of Hydroxyl radicals with Acetaldehyde over an Extended Temperature Range", P. H. Taylor, M. Sm. Rahman, A. Arif, B. Dellinger and P. Marshall, 26th International Symposium on Combustion, 497 (1996).
  52. "Computational Studies of the Reactions of CH3I with H and OH", P. Marshall, A. Misra and R. J. Berry, Chem. Phys. Lett., 265, 48 (1997).
  53. "A Computational Study of the Reactions of Atomic Hydrogen with Fluoromethanes: Kinetics and Product Channels", R. J. Berry, C. J. Ehlers, D. R. Burgess, Jr., M. R. Zachariah and P. Marshall, Chem. Phys. Lett., 269, 107 (1997).
  54. "A Computational Study of C-H Bond Strengths in Polyfluoroalkanes", P. Marshall and M. Schwartz, J. Phys. Chem., 101, 2906 (1997).
  55. "Kinetic Studies of the Reactions of Atomic Hydrogen with Iodoalkanes", J. Yuan, L. Wells and P. Marshall, J. Phys. Chem., 101, 3542 (1997).
  56. "Elementary Reactions and a Mechanism for the Suppression of Hydrogen Fires by CF3I", P. Marshall, A. Misra, J. Yuan, R. Berry and A. McIlroy, Proceedings of the 1997 Halon Options Technical Working Conference, 262 (1997).
  57. "Computational Studies of the Isomers of ClIO and ClIO2: Implications for the Stratospheric Chemistry of Iodine", A. Misra and P. Marshall, J. Chem. Soc. Faraday Trans. 93, 3301 (1997).
  58. "Potential Energy Surfaces for the Reaction of O-atoms with CH3I: Implications for Thermochemistry and Kinetics", A. Misra, R. J. Berry and P. Marshall, J. Phys. Chem. A. 101, 7420 (1997).
  59. "Ab Initio Calculations for Kinetic Modeling of Halocarbons", R. J. Berry, M. Schwartz and P. Marshall, in "Computational Thermochemistry: Prediction and Estimation of Molecular Thermodynamics" (K. K. Irikura, D. J. Frurip, Eds.; ACS Symp. Ser. 677; ACS: Washington DC, 1998) Ch. 18.
  60. "A Computational Study of the Reaction Kinetics of Methyl Radicals with Trifluorohalomethanes", R. J. Berry and P. Marshall, Int. J. Chem. Kinet., 30, 179 (1998).
  61. "Experimental and Computational Investigations of the Reaction of OH with CF3I and the Enthalpy of Formation of HOI", R. J. Berry, J. Yuan, A. Misra and P. Marshall, J. Phys. Chem. A, 102, 5182 (1998).
  62. "Computational Investigations of Iodine Oxides", A. Misra and P. Marshall, J. Phys. Chem. A, 102, 9056 (1998).
  63. "Kinetic Studies of the Reaction of Atomic Hydrogen with Trifluoroiodomethane", J. Yuan, L. Wells and P. Marshall, Chem. Phys. Lett., 297, 553 (1998).
  64. "Computational Study of the Kinetics of Hydrogen Abstraction from Fluoromethanes by the Hydroxyl Radical", M. Schwartz, P. Marshall, R. J. Berry, C. J. Ehlers and G. A. Petersson, J. Phys. Chem. A, 102, 10074 (1998).
  65. "Inhibition of Non-Premixed Flames by CF3Br", L. Truett, H. Thermann, D. Trees, K. Seshadri, J. Yuan, L. Wells and P. Marshall, 27th International Symposium on Combustion, 2741 (1998).
  66. "A Computational Study of the Enthalpies of Formation of Halomethylidynes", P. Marshall, A. Misra and M. Schwartz, J. Chem. Phys., 110, 2069 (1999).
  67. "The Thermochemistry of the Ethyl Radical and the C-H Bond Strength in Ethane", P. Marshall, J. Phys. Chem. A, 103, 4560 (1999).
  68. "Experimental and Ab Initio Investigations of the Kinetics of the Reaction H + H2S", J. Peng, X. Hu and P. Marshall, J. Phys. Chem. A, 103,5307 (1999).
  69. "An Ab Initio Investigation of Halocarbenes", M. Schwartz and P. Marshall, J. Phys. Chem. A, 103, 7900 (1999).
  70. "The Gas-Phase Kinetics of the Reactions of Alkali Metal Atoms with Nitric Oxide", A. Goumri, J.-D. R. Rocha, A. Misra and P. Marshall, J. Phys. Chem. A, 103, 9252 (1999).
  71. "Characterization of Reaction Pathways on the Potential Energy Surfaces for H + SO2 and HS + O2", A. Goumri, J.-D. R. Rocha, D. Laakso, C. E. Smith and P. Marshall, J. Phys. Chem. A, 103, 11328 (1999).
  72. "Kinetic and Mechanistic Studies of the Reaction of Hydroxyl Radicals with Tetrachloroethylene", L. B. Tichenor, A. El-Sinawi, T. Yamada, P. H. Taylor, J. Peng, X. Hu and P. Marshall, J. Phys. Chem. A, 104, 1700 (2000).
  73. "Reaction of Hydroxyl Radicals with Trichloroethylene: Evidence for Chlorine Elimination Channels at Elevated Temperatures", L. B. Tichenor, A. J. Lozada-Ruiz, T. Yamada, A. El-Sinawi, P. H. Taylor, J. Peng, X. Hu and P. Marshall, Proc. Combust. Inst., 28, 1495 (2000).
  74. "Kinetic Studies of the Reaction of Hydroxyl Radicals with Trichloroethylene and Tetrachloroethylene", L. B. Tichenor, A. El-Sinawi, T. Yamada, P. H. Taylor, J. Peng, X. Hu and P. Marshall, Chemosphere, 42, 571 (2001).
  75. "Rate Coefficients and Mechanistic Analysis for the Reaction of Hydroxyl Radicals with 1,1- Dichloroethylene and trans-1,2-Dichloroethylene over an Extended Temperature Range", T. Yamada, A. El-Sinawi, M. Siraj, P. H. Taylor, J. Peng, X. Hu and P. Marshall, J. Phys. Chem. A, 105, 7588 (2001).
  76. "Rate Coefficients and Mechanistic Analysis for Reaction of OH with Vinyl Chloride between 293 and 730 K", T. Yamada, M. Siraj, P. H. Taylor, J. Peng, X. Hu and P. Marshall, J. Phys. Chem. A, 105, 9436 (2001).
  77. "The Kinetics of the Reaction of H Atoms with C4F6", X. Hu, A. Goumri and P. Marshall, J. Phys. Chem. A, 105, 11220 (2001).
  78. "Rate Coefficient and Product Branching Measurements for the Reaction OH + Bromopropane from 230 to 360 K", M. K. Gilles, J. B. Burkholder, T. Gierczak, P. Marshall and A. R. Ravishankara, J. Phys. Chem. A, 106, 5358 (2002).
  79. "High-Accuracy Coupled-Cluster Computations of Bond Dissociation Energies in SH, H2S, and H2O", L. R. Peebles and P. Marshall, J. Chem. Phys., 107, 3132 (2002).
  80. "A Coupled-Cluster Study of the Enthalpy of Formation of Nitrogen Sulfide, NS", L. R. Peebles and P. Marshall, Chem. Phys. Lett., 366, 520 (2002).
  81. "A Computational Study of Chlorofluoro-Methyl Radicals", M. Schwartz, L.R. Peebles, R.J. Berry and P. Marshall, J. Chem. Phys., 118, 557 (2003).
  82. "Kinetic Studies of the Reactions of Hydroxyl Radicals with the Methyl-Substituted Silanes SiHn(CH3)4-n (n=0 to 4) at Room Temperature", A. Goumri, J. Yuan, E.L. Hommel and P. Marshall, Chem. Phys. Lett., 375, 149 (2003).
  83. "The Reaction of OH with Acetone and Acetone-d6 from 298 to 832 K: Rate Coefficients and Mechanism", T. Yamada, P.H. Taylor, A, Goumri and P. Marshall, J. Chem. Phys., 119, 10600 (2003).
  84. "An Investigation of the Reaction of CH3S with CO", L.C. Koch, P. Marshall, A.R. Ravishankara, J. Phys. Chem. A, 108, 5205 (2004).
  85. "Kinetic Studies of the Cl + HI Reaction using Three Techniques", J. Yuan, A. Misra, A. Goumri, D.D. Shao and P. Marshall, J. Phys. Chem. A, 108, 6857 (2004).
  86. "Reaction Kinetics of the Addition of Atomic Sulfur to Nitric Oxide", A. Goumri, D.D. Shao and P. Marshall, J. Chem. Phys., 121, 9999 (2004).
  87. "A Kinetic Study of the Reaction of Atomic Oxygen with SO2", J. Naidoo, A. Goumri and P. Marshall, Proc. Combust. Inst., 30, 1219 (2005).
  88. "Mechanism and Modeling of the Formation of Gaseous Alkali Sulfates", P. Glarborg and P. Marshall, Combust. Flame, 141, 22 (2005).
  89. "A Computational Study of the Thermochemistry of Bromine and Iodine-Containing Methanes and Methyl Radicals", P. Marshall, G.N. Srinivas and M. Schwartz, J. Phys. Chem. A, 109, 6371 (2005).
  90. "Modified Transition State Theory and Negative Apparent Activation Energies of Simple Metathesis Reactions: Application to the Reaction CH3 + HBr → CH4 + Br", L.N. Krasnoperov, J. Peng and P. Marshall, J. Phys. Chem. A, 110, 3110 (2006).
  91. "Thermal Dissociation of SO3 at 1000-1400 K", A. Yilmaz, L. Hindiyarti, A.K. Jensen, P. Glarborg and P. Marshall, J. Phys. Chem. A, 110, 6654 (2006).
  92. "Thermochemistry is not a Lower Bound to the Activation Energy of Endothermic Reactions: A Kinetic Study of the Gas-Phase Reaction of Atomic Chlorine with Ammonia", Y. Gao, I.M. Alecu, P-C. Hsieh, B.P. Morgan, P. Marshall and L.N. Krasnoperov, J. Phys. Chem. A, 110, 6844 (2006).
  93. "Kinetics of the NH + H2 Reaction and Reassessment of HNO Formation from NH + CO2, H2O", A. Fontijn, S.M. Shamsuddin, D. Crammond, P. Marshall and W.R. Anderson, Combust. Flame, 145, 543 (2006).
  94. "The Reaction of OH with Acetaldehyde and Deuterated Acetaldehyde: Further Insight into the Reaction Mechanism at both Low and Elevated Temperatures", P.H. Taylor, T. Yamada and P. Marshall, Int. J. Chem. Kinet., 38, 489 (2006).
  95. "The Relaxation of OH (v=1) and OD (v=1) by H2O and D2O at Temperatures from 251 to 390 K", D.C. McCabe, B. Rajakumar, P. Marshall, I.W.M. Smith and A.R. Ravishankara, Phys. Chem. Chem. Phys., 8, 4563 (2006).
  96. "Kinetics and Thermochemistry of the Addition of Atomic Chlorine to Acetylene", Y. Gao, I.M. Alecu, P.-C. Hsieh, A. McLeod, C. McLeod, M. Jones and P. Marshall, Proc. Combust. Inst., 31, 193 (2007).
  97. "Mechanisms of radical removal by SO2", C.L. Rasmussen, P. Glarborg and P. Marshall, Proc. Combust. Inst., 31, 339 (2007).
  98. "Metal ion-molecule kinetics at combustion temperatures: The reaction of Ca+ with O2", B. Cosic, A. Ermoline, A. Fontijn and P. Marshall, Proc. Combust. Inst., 31, 349 (2007).
  99. "Studies of the Kinetics and Thermochemistry of the Forward and Reverse Reaction Cl + C6H6 = HCl + C6H5", I. M. Alecu, Y. Gao, P-C. Hsieh, J.P. Sand, A. Ors, A. McLeod and P. Marshall, J. Phys. Chem. A., 111, 3970 (2007).
  100. "Reactions of SO3 with the O/H Radical Pool under Combustion Conditions", L. Hindiyarti, P. Glarborg and P. Marshall, J. Phys. Chem. A., 111, 3984 (2007).
  101. "A Kinetic Study of the Reaction of Atomic Hydrogen with Iodobenzene", Y. Gao, K. Fessel, C. McLeod and P. Marshall, Chem. Phys. Lett., 451, 8 (2008).
  102. "Computational Studies of the Thermochemistry of the Atmospheric Iodine Reservoirs HOI and IONO2", P. Marshall, Adv. Quantum Chem., 55, 159 (2008).
  103. "An Exploratory Study of Alkali Sulfate Aerosol Formation during Biomass Combustion", L. Hindiyarti, F. Frandsen, H. Livbjerg, P. Glarborg and P. Marshall, Fuel, 87, 1591 (2008).
  104. "Experimental Measurements and Kinetic Modeling of CO/H2/O2/NO2 Conversion at High Pressure", C. L. Rasmussen, J. Hansen, P. Marshall, and P. Glarborg, Int. J. Chem. Kinet., 40, 454 (2008).
  105. "Rate Constants and Hydrogen Isotope Substitution Effects in the CH3 + HCl and CH3 + Cl2 Reactions", A. J. Eskola, R. S. Timonen, P. Marshall, E. N. Chesnokov, and L. N. Krasnoperov, J. Phys. Chem. A, 112, 7391 (2008).
  106. "Kinetic Studies of Chlorobenzene Reactions with Hydrogen Atoms and Phenyl Radicals and the Thermochemistry of 1-Chlorocyclohexadienyl Radicals", Y. Gao and P. Marshall, Proc. Combust. Inst., 32, 351 (2009).
  107. "Experimental and Kinetic Modeling Study of C2H4 Oxidation at High Pressure", J.G. Lopez, C.L. Rasmussen, M.U. Alzueta, Y. Gao, P. Marshall and P. Glarborg, Proc. Combust. Inst., 32, 367 (2009).
  108. "Kinetic Studies of the Reaction of Atomic Chlorine with Chlorobenzene", Y. Gao and P. Marshall, Chem. Phys. Lett., 469, 266 (2009).
  109. "The Rate Constant for the CO + H2O2 Reaction", P. Glarborg and P. Marshall, Chem. Phys. Lett., 475, 40 (2009).
  110. "Enthalpy of Formation of the Cyclohexadienyl Radical and the C-H Bond Enthalpy of 1,4-Cyclohexadiene: An Experimental and Computational Re-Evaluation" Y. Gao, N.J. DeYonker, E. C. Garrett, III, A.K. Wilson, T.R. Cundari and P. Marshall, J. Phys. Chem. A, 113, 6955 (2009).
  111. "Atmospheric Chemistry of Isopropyl Formate and tert-Butyl Formate" A.S. Pimentel, G.S. Tyndall, J.J. Orlando, M.D. Hurley, T.J. Wallington, M.P.S. Andersen, P. Marshall, T.S. Dibble, Int. J. Chem. Kinet., 42, 479 (2010).
  112. "An Experimental and Theoretical Study of the Reaction between NH(X3Σ-) and SO(X3Σ-)" M.A. Blitz, R.J. Shannon, P. Marshall and M.J. Pilling, Z. Phys. Chem., 224, 1009 (2010).
  113. "High-Pressure Oxidation of C2H4/NO Mixtures" J. Gimenez-Lopez, M.U. Alzueta, C.T. Rasmussen, P. Marshall and P. Glarborg, Proc. Combust. Inst., 33, 449 (2011).
  114. "Kinetic and Modeling Studies of the Reaction S + H2S" Y. Gao, C. Zhou, K. Sendt, B.S. Haynes and P. Marshall, Proc. Combust. Inst., 33, 459 (2011).
  115. "Predicted Thermochemistry and Unimolecular Kinetics of Nitrous Sulfide" P. Marshall, Y. Gao and P. Glarborg, J. Chem. Phys., 135, 094301 (2011).
  116. "An Experimental and Computational Study of the Reaction of Ground-State Sulfur Atoms with Carbon Disulfide" Y. Gao and P. Marshall, J. Chem. Phys., 135, 144306 (2011).
  117. "Kinetic and theoretical investigations of the S + NO2 reaction" K.M. Thompson, Y. Gao and P. Marshall, Int. J. Chem. Kinet., 44, 90 (2012).
  118. "Inhibition of Hydrogen Oxidation by HBr and Br2" G. Dixon-Lewis, P. Marshall, B.Ruscic, A. Burcat, E. Goos, A. Cuoci, A. Frassoldati, T. Faravelli and P. Glarborg, Combust. Flame, 159, 528 (2012).
  119. "Fuel-Nitrogen Conversion in the Combustion of Small Amines using Dimethylamine and Ethylamine as Biomass-Related Model Fuels" A. Lucassen, K. Zhang, J. Warkentin, K. Mohammad, P. Glarborg, P. Marshall and K. Kohse-Hoeinghaus, Combust. Flame., 159, 2254 (2012).
  120. "Rate Constant for the Reaction C2H5 + HBr → C2H6 + Br" D.M. Golden, J. Peng, A. Goumri, J. Yuan and P. Marshall, J. Phys. Chem. A, 116, 5847 (2012).
  121. "Experimental and Kinetic Modeling Study of Methanol Ignition and Oxidation at High Pressure" V. Aranda, J. M. Christensen, M. U. Alzueta, P. Glarborg, S. Gersen, Y. Gao, P. Marshall, Int. J. Chem. Kinet., 45, 283 (2013).
  122. "Gas Phase Kinetics and Equilibrium of Allyl Radical Reactions with NO and NO2" M. P. Rissanen, D. Amedro, L. Krasnoperov, P. Marshall and R. S. Timonen, J. Phys. Chem. A, 113, 793 (2013).
  123. "Oxidation of Reduced Sulfur Species: Carbonyl Sulfide" P. Glarborg and P. Marshall, Int. J. Chem. Kinet., 45, 429 (2013).
  124. "Rate Constant and Branching Fraction for the NH2 + NO2 Reaction" S.J. Klippenstein, L.B. Harding, P. Glarborg, Y. Gao, H. Hu and P. Marshall, J. Phys. Chem. A, 117, 9011 (2013).
  125. "Kinetic studies of the reaction NH2 + H2S" Y. Gao and P. Marshall, Chem. Phys. Lett., 594, 30 (2014).
  126. "Oxidation of Reduced Sulfur Species: Carbon Disulfide" P. Glarborg, B. Halaburt, P. Marshall, A. Guillory, J. Troe, M. Thellefsen and K. Christensen, J. Phys. Chem. A, 118, 6798-6809 (2014).
  127. "Computational Study of the Thermochemistry of N2O5 and the Kinetics of the Reaction N2O5 + H2O → 2 HNO3" I. M. Alecu and P. Marshall, J. Phys. Chem. A, 118, 11405-11416 (2014).
  128. "Ab Initio and Kinetic Modeling Studies of Formic Acid Oxidation" P. Marshall and P. Glarborg, Proc. Combust. Inst., 35, 153-160 (2015).
  129. "Kinetic Studies of the Reaction of Atomic Sulfur with Acetylene" S. Ayling, Y. Gao and P. Marshall, Proc. Combust. Inst., 35, 215-222 (2015).
  130. "Rate Constant and Thermochemistry for K+O2+N2 = KO2+N2" T. Sorvajarvi, J. Viljanen, J. Toivonen, P. Marshall and P. Glarborg, J. Phys. Chem. A, 119, 3329-3336 (2015).
  131. "High-Temperature Kinetics of the Reaction between Chlorine Atoms and Hydrogen Sulfide" Y. Gao, I. M. Alecu, A. Goumri and P. Marshall, Chem. Phys. Lett., 624, 83-86 (2015).
  132. "Temperature- and Pressure-Dependence of the Reaction S + CS (+M) → CS2 (+M)" P. Glarborg, P. Marshall and J. Troe, J. Phys. Chem. A, 119, 7277-7281 (2015).
  133. "Glyoxal Oxidation Mechanism: Implications for the Reactions HCO + O2 and OCHCHO + HO2" N. Fassheber, G. Friedrichs, P. Marshall and P. Glarborg, J. Phys. Chem. A, 119, 7305-7315 (2015).
  134. "Experimental and Computational Studies of the Kinetics of the Reaction of Atomic Hydrogen with Methanethiol" K.E. Kerr, I.M. Alecu, K.M. Thompson, Y. Gao and P. Marshall, J. Phys. Chem. A, 119, 7352-7360 (2015).
  135. "The Reaction Kinetics of Amino Radicals with Sulfur Dioxide" Y. Gao, P. Glarborg and P. Marshall, Z. Phys. Chem., 229, 1649-1661 (2015).
  136. "The Spin-Forbidden Reaction of Ground-State Sulfur Atoms with Ethylene" K.M. Thompson, Y. Gao and P. Marshall, Int. J. Chem. Kinet., 48, 124-130 (2016).
  137. "Ammonia Oxidation at High Pressure and Intermediate Temperatures" Y. Song, H. Hashemi, J.M. Christensen, C. Zou, P. Marshall and P. Glarborg, Fuel, 181, 358-365 (2016).
  138. "Experimental and Kinetic Modeling Study of C2H2 Oxidation at High Pressure" J. Gimenez-Lopez, C.T. Rasmussen, H. Hashemi, M. U. Alzueta, Y. Gao, P. Marshall, C. F. Goldsmith and P. Glarborg, Int. J. Chem. Kinet., 48, 724-738 (2016).
  139. "Relative Rate and Product Studies of the Reactions of Atomic Chlorine with Tetrafluoroethylene, 1,2-Dichloro-1,2-difluoroethylene, 1,1-Dichloro-2,2-difluoroethylene, and Hexafluoro-1,3-butadiene in the Presence of Oxygen" T.N. Herath, E.C. Clinch, I. Orozco, E.L. Raign and P. Marshall, J. Phys. Chem. A, 120, 7311-7319 (2016).
  140. "An Exploratory Flow Reactor Study of H2S Oxidation at 30-100 Bar" Y. Song, H. Hashemi, J.M. Christensen, C. Zou, B.S. Haynes, P. Marshall and P. Glarborg, Int. J. Chem. Kinet., 49, 37-52 (2017).
  141. "Importance of the Hydrogen Isocyanide Isomer in Modeling Hydrogen Cyanide Oxidation in Combustion" P. Marshall and P. Glarborg, Energy Fuels, 31, 2156-2163 (2017).
  142. "Representing Global Reactive Potential Energy Surfaces Using Gaussian Processes" B. Kolb, P. Marshall, B. Zhao, B. Jiang and H. Guo, J. Phys. Chem. A, 121, 2552-2557 (2017).
  143. "Experimental and Theoretical Studies of the Reactions of Ground-State Sulfur Atoms with Hydrogen and Deuterium" K.M. Thompson, Y. Gao, P. Marshall, H. Wang, L. Zhou, Y. Li and H. Guo, J. Chem. Phys., 147, 134302 (2017).
  144. "Relative Rate Studies of the Reactions of Atomic Chlorine with Acetone and Cyclic Ketones" T.N. Herath, I. Orozco, E.C. Clinch and P. Marshall, Int. J. Chem. Kinet., 50, 41-46 (2018).
  145. "Ab Initio Calculations and Kinetic Modeling of Thermal Conversion of Methyl Chloride: Implications for Gasification of Biomass" M. Singla, M.L. Rasmussen, H. Hashemi, H. Wu, P. Glarborg, M. Pelucchi, T. Faravelli and P. Marshall, Phys. Chem. Chem. Phys., 20, 10741-10752 (2018).
  146. "Global Warming Potential Estimates for the C1-C3 Hydrochlorofluorocarbons (HCFCs) included in the Kigali Amendment to the Montreal Protocol" D.K. Papanastasiou, A. Beltrone, P. Marshall and J.B. Burkholder, Atmos. Chem. Phys., 18, 6317-6330 (2018).
  147. "Rate Coefficient Measurements and Theoretical Analysis of the OH + (E)-CF3CH=CHCF3 Reaction" M. Baasandorj, P. Marshall, R.L. Waterland, A.R. Ravishankara and J.B. Burkholder, J. Phys. Chem. A, 122, 4635-4646 (2018).
  148. "Experimental and Computational Studies of the Kinetics of the Reaction of Hydrogen Atoms with Carbon Disulfide" K.E. Kerr, Y. Gao and P. Marshall, Proc. Combust. Inst., 37, 373-379 (2019).
  149. "The C2H2 + NO2 Reaction: Implications for High Pressure Oxidation of C2H2/NOx Mixtures" P. Marshall, C. Leung, J. Gimenez-Lopez, C.T. Rasmussen, H. Hashemi, P. Glarborg, M. Abian, M.U. Alzueta, Proc. Combust. Inst., 37, 469-476 (2019).
  150. "UV and Infrared Absorption Spectra and 248 nm Photolysis of Maleic Anhydride ( C4H2O3)" P. Marshall, V.C. Papadimitriou, D.K. Papanastasiou, J.M. Roberts and J.B. Burkholder, J. Photochem. Photobiol. A, 382, 111953 (2019).
  151. "Climate Metrics for C1-C4 Hydrofluorocarbons (HFCs)" J.B. Burkholder, P. Marshall, P.P. Bera, J.S. Francisco and T.J. Lee, J. Phys. Chem. A, 124, 4793-4800 (2020).
  152. "Temperature-Dependent Rate Coefficients for the Gas-Phase OH + Furan-2,5-dione (C4H2O3, Maleic Anhydride) Reaction" A. Chattopadhyay, V.C. Papadimitriou, P. Marshall and J.B. Burkholder, Int. J. Chem. Kinet., 52, 623-631 (2020).
  153. "Oxidation of Methylamine" P. Glarborg, C.S. Andreasen, H. Hashemi, R. Qian and P. Marshall, Int. J. Chem. Kinet., 52, 893-906 (2020).
  154. "Ignition Delay Times of NH3/DME Blends at High Pressure and Low DME fraction: RCM Experiments and Simulations" L. Dai, H. Hashemi, P. Glarborg, S. Gersen, P. Marshall, A. Mokhov and H. Levinsky, Combust. Flame, 227, 120-134 (2021).
  155. "Kinetic Fall-Off Behavior for the Cl + Furan-2,5-dione (C4H2O3, Maleic Anhydride) Reaction" A. Chattopadhyay, T. Gierczak, P. Marshall, V.C. Papadimitriou and J.B. Burkholder, Phys. Chem. Chem. Phys., 23, 4901-4911 (2021).
  156. "Acetaldehyde Oxidation at High Pressure" H. Hashemi, J.M. Christensen, P. Marshall and P. Glarborg, Proc. Combust. Inst., 38, 269-278 (2021).
  157. "Experimental and Kinetic Modeling Study of Oxidation of Acetonitrile" M.U. Alzueta, M. Guerrero, A. Millera, P. Marshall and P. Glarborg, Proc. Combust. Inst., 38, 575-583 (2021).
  158. "Selective Noncatalytic Reduction of NOx using Ammonium Sulfate" K.R.K. Krum, M. Jensen, S. Li, T. Norman, P. Marshall, H. Wu and P. Glarborg, Energy Fuels, 35, 12392-12402 (2021).
  159. "Theoretical Modeling Study of the Reaction H + CF4 → HF + CF3" C.J. Cobos, G. Knight, P. Marshall and J. Troe, Int. J. Chem. Kinet., 53, 939-945 (2021).
  160. "New Reactions of Diazene and Related Species for Modelling Combustion of Amine Fuels" P. Marshall, G. Rawling and P. Glarborg, Mol. Phys., 119, e1979674 (2021).
  161. "Computational study of the gas-phase reactions of sulfuric acid with OH(2PJ), O(3PJ), Cl(2PJ) and O(1D) radicals" P. Marshall and J.B. Burkholder, Chem. Phys. Lett., 787, 139203 (2022).
  162. "Challenges in Kinetic Modeling of Ammonia Pyrolysis" P. Glarborg, H. Hamid and P. Marshall, Fuel Commun., 10, 100049 (2022).
  163. "Gas-Phase Chemistry of 1,1,2,3,3,4,4-Heptafluorobut-1-ene Initiated by Chlorine Atoms" R. Sapkota and P. Marshall, Molecules, 27, 647 (2022).
  164. "An Experimental and Modeling Study on Auto-Ignition Kinetics of Ammonia/Methanol Mixtures at Intermediate Temperature and High Pressure" M. Li, X. He, H. Hashemi, P. Glarborg, V.M. Lowe, P. Marshall, R. Fernandes and B. Shu, Combust. Flame, 242, 112160 (2022).
  165. "Participation of Alkali and Sulfur in Ammonia Combustion Chemistry: Investigation for Ammonia/Solid Fuel Co-Firing Applications" W. Weng, Z. Li, P. Marshall and P. Glarborg, Combust. Flame, 244, 112236 (2022).
  166. "Comment on 'Extremely rapid self-reactions of hydrochlorofluoromethanes and hydrochlorofluoroethanes and implications in destruction of ozone'" P. Marshall and J.B. Burkholder, Chem. Phys. Lett., 800, 139411 (2022).
  167. "Experimental and Computational Studies of the Kinetics of the Reaction of Hydrogen Peroxide with the Amidogen Radical" I.M. Alecu, Y. Gao and P. Marshall, J. Chem. Phys., 157, 014304 (2022).
  168. "Optical in-situ measurements and modeling of post-flame sulfation of NaOH(g) and NaCl(g)" D. Schmid, W. Weng, S. Li, O. Karlström, M. Hupa, Z. Li, P. Glarborg, P. Marshall and M. Aldén, Fuel, 332, 126337 (2023).
  169. "An experimental and chemical kinetic modeling study of the role of potassium in the moist oxidation of CO" A. Chanpirak, H.Wu, P. Glarborg and P. Marshall, Fuel, 335, 127075 (2023).
  170. "Measurement of the Intramolecular Hydrogen-Shift Rate Coefficient for the CH3SCH2OO Radical between 314 and 433 K" E. Assaf, Z. Finewax, P. Marshall, P.R. Veres, J.A. Neuman and J.B. Burkholder, J. Phys. Chem. A, 127, 2336-2350 (2023).
  171. "The chemical coupling between moist CO oxidation and gas-phase potassium sulfation" A. Chanpirak, H. Hashemi, F.J. Frandsen, H. Wu, P. Glarborg and P. Marshall, Fuel, 336, 127127 (2023).
  172. "Probing high-temperature amine chemistry: is the reaction NH3 + NH2 = N2H3 + H2 important?" P. Marshall and P. Glarborg, J. Phys. Chem. A, 127, 2601-2607 (2023).
  173. "Experimental and Modeling Study of Water Time Histories during H2S-N2O Combustion in a Shock Tube" S.P. Cooper, P. Marshall, O. Mathieu, L.T. Pinzón, C.R. Mulvihill, P. Glarborg and E.L.Petersen, Proc. Combust. Inst., 39, 487-497 (2023).
  174. "Reactions of Hydrazine with the Amidogen Radical and Atomic Hydrogen" Y. Gao, I.M. Alecu, H. Hashemi, P. Glarborg and P. Marshall, Proc. Combust. Inst., 39, 571-579 (2023).
  175. "Re-Examination of the N2O + O Reaction" P. Glarborg, J.S. Allingham, A.B. Skov, H. Hashemi and P. Marshall, J. Phys. Chem. A, 127, 6521-6531 (2023).
  176. "Re-Evaluation of Rate Constants for the Reaction N2H4 (+ M) ⇄ NH2 + NH2 (+ M)" C.J. Cobos, P. Glarborg, P. Marshall and J. Troe, Combust. Flame, 257 112374 (2023).
  177. "An Experimental, Theoretical, and Kinetic Modeling Study of Gas-Phase Sulfation of KCl" A. Chanpirak, H. Wu, P. Marshall and P. Glarborg, Fuel, 363 130974 (2024).
  178. "Kinetics and Thermochemistry of Hydroxyacetonitrile (HOCH2CN) and Its Reaction with Hydroxyl Radical" P. Marshall and J.B. Burkholder, ACS Earth Space Chem., DOI 10.1021/acsearthspacechem.4c00176 (2024).